高铁酸盐的电合成及其作为电极材料的电化学性质研究进展

综述了近几年来在高铁酸盐电合成及其作为电池材料的电化学性质研究方面的进展，介绍了各类不同的铁阳极在碱性电解质溶液中电解氧化为高铁酸盐的电流效率，并对在直流电上叠加正弦式交流电的电化学过程进行了讨论。高铁酸盐作为电池的阴极材料能形成高性能的超级铁电池。参考文献32篇。     

取代苯体系的二阶非线性光学性质:动力学李代数方法

提出了一种动力学李代数方法来研究取代苯体系的非线性光学性质. 对于给定的PPP模型(Pariser-Parr-Pople)哈密顿量, 生成了一个动力学李代数. 依据这些代数元构造出演化算子作为群参数的函数, 通过求解一组非线性微分方程能够得到这些群参数. 再按照统计力学中的密度算子公式给出取代苯分子体系偶极矩的统计平均值. 于是导出二阶极化率的表达式. 与其他量子力学计算结果比较, 表明这种动力学李代数方法在预言有机共轭分子的非线性光学性质上同样有用.     

Synthesis of a Polymer-bound Sensitizer and its Application in the Photoisomerization of trans-Vitamin D_3 to cis-Vitamin D_3

The photochemistry of the vitamin D family and their precursors has been the subject of extensive studies for many years1-4. Most of the studies focus on the photoisomer- ization of 7-dehydrocholesterol and that of tachysterol to previtamin D3, which is of commercial importance in the synthesis of vitamin D34, 5. Recently the cis/trans isomerization of vitamin D analogs (Scheme 1) draws attention because of its importance in the synthesis of hydroxylated vitamin D metabolites6. However, o…     

咪唑类配体与双过氧钒配合物相互作用的NMR研究

为探讨咪唑环上取代基团对反应平衡的影响, 在模拟生理条件(0.15 mol·L-1 NaCl溶液)下, 应用多核(1H、13C和51V)、扩散排序谱(DOSY)以及变温NMR等谱学技术研究双过氧钒配合物NH4[OV(O2)2{2-(2’-Pyri-dine)-Imidazole}]·4H2O(简写为bpV(Imi-Py))和咪唑类配体(咪唑、2-甲基鄄咪唑、4-甲基-咪唑和组氨酸)的相互作用, 其从强到弱的顺序为咪唑≈4-甲基-咪唑>2-甲基-咪唑>组氨酸. 研究结果表明, 咪唑环上取代基团空间位阻对反应平衡产生较大影响,同时竞争配位的结果导致新的6 配位过氧物种[OV(O2)2L]-(L 为咪唑类配体)的生成, 当配体为4-甲基-咪唑和组氨酸时, 生成的则是一对异构体.     

Cd2Ge7O16中Tb的长余辉发光特性

本文研究了Cd₂Ge₇O₁₆∶Tb³⁺材料的发光及其长余辉性质。指出Tb³⁺的发光是该离子的 ⁵D₃- ⁷D_J、 ⁵D₄- ⁷D_J两种跃迁产生的；随着掺杂浓度的增加 ⁵D₄- ⁷D_J跃迁增强，发光颜色由蓝变绿。并把该材料的长余辉性质归结为基质结构中有电子陷阱和空穴陷阱。提出余辉机理模型。     

Ionic Liquid Based Electrolyte with Mesoporous Silica SBA-15 as Framework for Quasi-solid-state Dye-sensitized Solar Cells

Quasi-solid-state electrolytes were fabricated with mesoporous silica SBA-15 as a framework material. Ionic conductivity measurements revealed that SBA-15 can enhance the conductivity of the quasi-solid-state electrolyte. The diffusion coefficients of polyiodide ions such as Ⅰ3ˉ and Ⅰ5ˉ which were confirmed by Raman spectroscopic measurement, were about twice larger than that of I-. The optimized photoenergy conversion efficiency of dye-sensitized solar cells （DSSC） with the quasi-solid-state electrolyte was 4.3% under AM 1.5 irradiation at 75 mW·cm^-2 light intensity.     

嘌呤衍生物在葫芦［6］脲单轮烷键合固定相上的色谱行为

在反相和正相色谱模式下,研究了几种嘌呤衍生物在葫芦［6］脲单轮烷键合硅胶固定相上的高效液相色谱行为,并在反相模式下与ODS固定相进行了比较,考察了流动相中甲醇含量、流动相pH值和离子强度对嘌呤化合物保留的影响。研究结果表明:在反相模式下,嘌呤化合物与葫芦［6］脲单轮烷键合相之间存在多种相互作用,除疏水作用外,分离过程中还存在与ODS不同的色谱分离机制。在正相条件下,多作用力的色谱分离机制同样存在。葫芦［6］脲单轮烷键合相与溶质之间存在疏水、氢键、π-π和偶极-偶极等多种作用力,协同作用提高了固定相对嘌呤化合物的分离选择性。     

CHEMOTHERAPEUTIC POLYMERS Ⅻ. SYNTHESIS AND ANTITUMOR ACTIVITY OF POLYAMIDES CONTAINING 5-FLUOROURACILS AS PENDANT GROUP

Six polyamides with pendant 5-fluorouracil group were synthesized by the polycondensation ofdi-p-nitrophenyl N-(5-fluorouracil-1-acetyl)glutamate with a series of polymethylene diamines.All of the new polyamides obtained are soluble in water. Their chemical structures were confirmedby ~1H NMR, UV and IR spectra as well as elemental analyses. The antitumor activity of some ofthese polyamides were tested against Ehrlich Ascites Carcinoma in mice, III_a showed an inhibitionrate of 43%.     

腔长失调对光腔衰荡法测量精度的影响

 只考虑腔长失调因素下建立了反射率模拟测量的理论模型。根据高斯光束传输规律分析了腔长失调对衰荡腔模式耦合的影响，推导了腔长失调与谐振腔输出脉冲信号、衰荡信号与反射率之间的关系，模拟了腔长失调在±10mm范围内的光脉冲衰荡现象。结果表明：对于光敏面直径为0.2mm的高速探测器，为了保证10^-6的测量精度，腔长的失调量应控制在±1mm之间。在光路调节中采用具有对数变换功能的示波器和动态范围较大的探测器，可以提高测量精度。     

A New Sandwiched-type Polyoxotungstate Containing {Cd4} Transition-metal Cluster： Synthesis,Structure and Luminescent Property

A new sandwiched polyoxometalate [HK11Cd4Cl2（PW9034）2]·18H2O （1）, incor- porating a unique hybrid tetranuclear cadmium cluster （abbreviated to {Cd4}） with two trivacant polyanions [B-α-PW9O34]9-, has been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectroscopy, UV-vis, and single-crystal X-ray diffraction analysis. Crystal data for 1： monoclinic, space group C2/c, a = 19.2997（4）, b = 13.8014（3）, c = 31.9819（8） A, β = 102.764（2）°, V= 8308.3（3） A3, Z = 4, P2O86Cl2K11Cd4W18H37, Mr = 5735.13, Dc = 4.584 mg-mm-3, F（000） = 10084, μ = 26.579 mm-1, the final R = 0.0378 and wR = 0.0989 for 6558 observed reflections （I〉 2σ（I））. X-ray crystallographic study shows that the molecular structure of 1 contains four cadmium atoms. Two CdO6 distorted octahedra and two CdOsC1 distorted octahedra combine with each other in turn via edge-sharing, resulting in a regular rhomb-like cluster sandwiched between two {B-a-PW9034} units. Further, the sandwich-type polyoxoanions were connected by K＋ ions to form a complicated 3-D open-framework through connecting with each terminal O atom of the [Cd4C12（PW9O34）2]12- polyoxoanions. In addition, compound 1 exhibits photoluminescence property at room temperature and the band gap can be assessed at 3.25 eV.